闫冰 教授 博士生导师

联系电话 021-65983921
Email byan@tongji.edu.cn
专业方向 无机化学
办公室 021-65983921, 65984663
研究方向 稀土化学、杂化材料、微纳固体
个人介绍

简历：

1970年12月生于吉林省长春市

1992年7月 哈尔滨工业大学 工学学士

1995年7月 哈尔滨工业大学 工学硕士

1998年7月 中国科学院长春应用化学研究所 理学博士

1998年8月至2001年9月 香港城市大学 研究助理，北京大学、舍布鲁克大学 博士后研究员

2001年11月 同济大学化学系 教授、博士生导师

主讲课程：

本科生课程：普通化学、中国近现代科学技术史等；研究生课程：稀土化学、现代无机合成与制备化学、材料发光导论、无机/有机杂化材料等。

研究领域及方向： 稀土、无机有机杂化、纳米复合、微纳固体、光物理、磁化学

1 稀土/无机/有机/高分子杂化材料体系的协同设计、化学键构筑与组装

2 稀土功能化合物及微纳米固体的温和控制合成、相结构、微结构和光磁性质

3 高值化稀土基发光及相关功能材料及其在相关交叉领域的研制、应用及开发

科研成果：

近年来作为通讯作者在Chem. Commun.、Chem. Eur. J.、Chem. Asi. J.、J. Mater. Chem.、Inorg. Chem.、J. Phys. Chem. B / C.、Dalton Trans.等被SCI收录的国际重要英文期刊发表学术研究论文200余篇。被他引3000余次，H指数34。授权发明专利20余项。

作为主要完成人参加国家自然基金重点项目子课题(2项)，国家重点基础研究规划项目(973)子课题，国家自然基金面上项目，中国科学院重大基金项目等。作为负责人主持国家自然科学基金项目(4项)。
　　曾获得中国科学院院长奖学金、中国科学院稀土化学与物理重点实验室青年科学一等奖等。入选教育部2008年度新世纪优秀人才支持计划。现为上海市稀土学会理事，中国稀土学会稀土发光专业委员会委员。

已培养毕业博士生15名，硕士生27名。目前重点集中于稀土无机/有机高分子杂化复合材料与与稀土功能化合物-微纳米固体材料两个领域并向交叉、应用开发方向拓展。欢迎国内外有志于无机化学、材料化学与稀土科学研究的青年学子报考博士生、硕士生和从事博士后研究。

近期代表论文：

1 Y. J. Gu, B. Yan*, “Novel photoversion lanthanide functionalized SBA-15 mesoporous hybrids: ultraviolet-visible excitation and visible-NIR emission”, Eur. J. Inorg. Chem. 2013, accepted. 

2 闫冰,《无机-有机杂化纳米孔材料的功能化组装、光物理性质及应用化学》，《纳米孔材料化学：催化与功能化》第6章，197-232，于吉红、闫文付主编，科学出版社、2013。

3 Y. Zhao, B. Yan*, “Rare earth (Eu3+, Tb3+) / β-diketonate functionalized mesoporous SBA-15 / GaN nanocomposites: multi-component chemical bonding assembly, characterization and luminescence”, J. Coll. Interf. Sci. 2013, 395, 145-153.

4 Y. Y. Li, B. Yan*, Q. P. Li, “Bifunctional heterometallic Ln3+-Gd3+ (Ln = Eu, Tb) hybrid silica microspheres: luminescence and MRI contrast agent property”, Dalton Trans. 2013, 42, 1678-1686.

5 Y. F. Shao, B. Yan*, “Magnetic mesoporous silica nanospheres-supported europium (III) tetrakis(β-diketonate) complexes using ionic liquid compound as linker”, Eur. J. Inorg. Chem. 2013, 381-387.  

6 Y. J. Gu, B. Yan*, “Lanthanide mesoporous SBA-15 hybrids through functionalized 6-hydroxybenz[de]anthracen-7-one linkage: UV-visible light sensitization and visible-NIR luminescence”, J. Coll. Interf. Sci. 2013, 393, 36-43.

7 Y. Y. Li, B. Yan*, X. F. Qiao, “Visible light excitation and near-infrared luminescence of lanthanide mesoporous hybrids through 9-hydroxyphenalen-1-one linkage by chemical bonds”, Microp. Mesop. Mater. 2013, 169, 60-66.

8 Q. Zhang, B. Yan*, F. Lei, H. H. Chen, “Organic salt assisted colloidal synthesis and X-ray luminescence of (Tm, Tb, Eu)-doped LaOBr nanocrystals”, Nanoscale 2012, 4, 7646-7648.

9 Q. P. Li, B. Yan*, “Luminescent GaN semiconductor based on surface modification with lanthanide complexes through an ionic liquid bridge”, RSC Adv. 2012, 2, 10840-10843.

10 B. Yan*, “Recent progress on photofunctional lanthanide hybrid materials”, RSC Adv. 2012, 2, 9304-9324.(Invited Review)

11 Y. F. Shao, B. Yan*, Z. Y. Jiang, “Multicomponent assembly of luminescent hybrid materials of ZnO-lanthanide polymer complex functionalized SBA-15 mesoprous host by chemical bonds”, RSC Adv. 2012, 2, 9192-9200.

12 Q. P. Li, B. Yan*, “Luminescent hybrid materials of Lanthanide β-diketonate and mesoporous host through the covalent and ion bonding with anion metathesis”, Dalton Trans. 2012, 41, 8567-8574.

13 Q. P. Li, B. Yan*, “Multi-walled carbon nanotube based ternary rare earth (Eu3+, Tb3+) hybrid materials with organically modified silica-oxygen bridge”, J. Coll. Interf. Sci. 2012, 380, 67-74.

14 Y. F. Shao, B. Yan*, “Photofunctional hybrids of rare earth complexes covalently bonded to ZnO core-shell nanoparticles substrate through polymer linkage”, Dalton Trans. 2012, 41, 7423-7430.

15 B. Yan*, Y. Y. Li, X. F. Qiao, “Photofunctional metalloporphrines functionalized mesoporous hybrids phen-Ln(LSi)-SBA-15 (Ln = Nd, Yb, L = porphyrin derivatives”, Microp. Mesop. Mater. 2012, 158, 129-136.

16. Q. Zhang, B. Yan*,“Salt effect based synthesis and anomalous magnetic properties of rare-earth oxide nanosheets with sub-1-nm thickness”, Chem. Eur. J. 2012, 18, 5150-5154.

17. Y. Zhao, B. Yan*, “Rare earth hybrid materials of organically modified silica covalently bonded GaN matrix: multicomponent assembly and multi-color luminescence”, Dalton Trans. 2012, 41, 5334-5342.

18. Y. Y. Li, B. Yan*, L. Guo, Y. J. Li, “Ternary lanthanide sulfoxide-functionalized mesoporous hybrids Phen-RE(OBDS(BSAB))3-SBA-15 (RE = Eu, Tb): covalently bonded assembly, characterization, and photoluminescence”, Microp. Mesop. Mater. 2012, 148, 73-79.

19. B. Yan*, Y. J. Li, “Photoactive lanthanide (Eu3+, Tb3+) centered hybrid systems with titania-mesoporous silica / aluminum mesoporous silica based hosts”, J. Mater. Chem. 2011, 21, 18454-18461.

20. B. Yan*, L. M. Zhao, X. F. Qiao, X. L. Wang, Y. Zhao, “Sol-gel preparation, microstructure and luminescence of rare earth / silica / polyacrylamide hybrids through double functionalized covalent Si-O linkage”, RSC Adv. 2011, 1, 1064-1071.

21. L. Guo, L. S. Fu, R. A. S. Ferreira, L. D. Carlos, Q. P. Li, B. Yan*, “Novel lanthanide luminescent materials based on multifunctional complexes of 2-sulfanylpyridine-3-carboxylic acid and silica/titania hosts”, J. Mater. Chem. 2011, 21, 15600-15607.

22. Y. J. Li, B. Yan*, L. Wang, “Calix[4]arene derivative functionalized lanthanide (Eu, Tb) SBA-15 mesoporous hybrids with covalent bond: assembly, characterization and photoluminescence”, Dalton Trans. 2011, 40, 6722-6731.

23. Y. J. Li, B. Yan*, “Preparation, characterization and luminescence properties of the ternary europium complexes covalently bonded to titania and mesoporous SBA-15”, J. Mater. Chem. 2011, 21, 8129-8136.

24. Q. Zhang, B. Yan*, “Phase control of upconversion nanocrystals and new rare earth fluorides through diffusion-controlled strategy in hydrothermal system”, Chem. Commun. 2011, 47, 5867-5869.

25. L. Guo, B. Yan*, J. L. Liu, “Photofunctional Eu3+/Tb3+ hybrids through sulfoxide linkages: coordination bonds construction, characterization and luminescence”, Dalton Trans. 2011, 40, 4933-4940.

26. X. F. Qiao, B. Yan*, “Rare earth (Eu3+, Tb3+) centered polymeric hybrids: composite assembly of radical addition polymerization and condensation reaction, physical characterization and photoluminescence”, New J. Chem. 2011, 35, 568-575.

27. C. Wang, B. Yan*, J. L. Liu, L. Guo, “Photoactive europium hybrids of b-diketone-modified polysilsesquioxane bridge linking Si-O-B(Ti)-O xerogels”, Eur. J. Inorg. Chem. 2011, 879-887.

28. J. L. Liu, B. Yan* “Lanthanide-centered organic-inorganic hybrids through a functionalized aza-crown ether bridge: coordination bonding assembly, microstructure and multicolor luminescence”, Dalton Trans. 2011, 40, 1961-1968.

29. Y. J. Li, L. Wang, B. Yan*, “Photoactive lanthanide hybrids covalently bonded to functionalized periodic mesoporous organosilica (PMO) by calix[4]arene derivative”, J. Mater. Chem. 2011, 21, 1130-1138.

30. L. Guo, B. Yan*, K. Sheng, X. L. Wang, “Coordination bonding construction, characterization and photoluminescence of ternary lanthanide (Eu3+, Tb3+) hybrids with phenylphenacyl-sulfoxide modified bridge and polymer units”, Dalton Trans. 2011, 40, 632-638.

31. X. F. Qiao, H. Y. Zhang, B. Yan*, “Photoactive binary and ternary lanthanide (Eu3+, Tb3+, Nd3+) hybrids with p-tert-butylcalix[4]arene derived Si-O linkages and polymers”, Dalton Trans. 2010, 39, 8882-8892.

32. L. L. Kong, B. Yan*, Y. J. Li, Y. Li, “Photoactive metallic (Al3+, Zn2+, Eu3+, Tb3+, Er3+, Nd3+) mesoporous hybrid materials by functionalized 8-hydroxyquinolinate linkage covalently bonded SBA-15”, Microp. Mesop. Mater. 2010, 135, 45-50.

33. Q. Zhang, B. Yan*, “Hydrothermal synthesis and characterization of LiREF4 (RE = Y, Tb-Lu) nanocrystals and their core-shell nanostructures”, Inorg. Chem. 2010, 49, 6834-6839.

34. K. Sheng, B. Yan*, H. F. Lu, L. Guo, “Ternary rare earth inorganic/organic hybrids with a mercapto-functionalized Si-O Linkage and a polymer chain: coordination bonding assembly and luminescence”, Eur. J. Inorg. Chem. 2010, 3498-3505.

35. Y. J. Li, B. Yan*, Y. Li, “Lanthanide (Eu3+, Tb3+) centered mesoporous hybrids with 1,3-diphenyl-1,3-propanepione covalently linking SBA-15 (SBA-16) and poly(methylacrylic acid)”, Chem. Asi. J. 2010, 5, 1642-1651.

36. J. L. Liu, B. Yan*, L. Guo, “Photoactive ternary lanthanide-centered hybrids with Schiff-base functionalized polysilsesquioxanes bridges and N-heterocylic ligands”, Eur. J. Inorg. Chem. 2010, 2290-2296.

37. Y. Li, B. Yan*, Y. J. Li, “Sulfide functionalized lanthanide (Eu/Tb) periodic mesoporous organosilicas (PMOs) hybrids with covalent bond: physical characterization and photoluminescence”, Microp. Mesop. Mater. 2010, 132, 87-93.

38. Y. J. Li, B. Yan*, “Photoactive europium(III) centered mesoporous hybrids with 2-thenoyltrifluoroacetone functionalized SBA-16 and organic polymers”, Dalton Trans. 2010, 39, 2554-2562.

39. Y. J. Li, B. Yan*, Y. Li, “Luminescent lanthanide (Eu3+, Tb3+) ternary mesoporous hybrids with functionalized b-diketones (TTA, DBM) covalently linking SBA-15 and 2,2’-bipyridine (bpy)”, Microp. Mesop. Mater. 2010, 131, 82-88.

40. L. Guo, B. Yan*, “Chemically bonding assembly, physical characterization, and photophysical properties of lanthanide hybrids from a functional thiazole bridge”, Eur. J. Inorg. Chem. 2010, 1267-1274.

41. B. Yan*, Y. Li, “Luminescent ternary inorganic-organic mesoporous hybrids Eu(TTASi-SBA-15)phen: covalent linkage in TTA directly functionalized SBA-15”, Dalton Trans. 2010, 39, 1480-1487.

42. Y. Li, B. Yan*, “Lanthanide (Tb3+, Eu3+) functionalized MCM-41 through modified meta-aminobenzoic acid linkage: covalently bonding assembly, physical characterization and photoluminescence”, Microp. Mesop. Mater. 2010, 128, 62-70.

43. X. F. Qiao, B. Yan*, “Binary and ternary lanthanide centered hybrid polymeric materials: coordination bonding construction, characterization, microstructure and photoluminescence”, Dalton Trans. 2009, 38, 8509-8518.

44. Y. J. Li, B. Yan*, “Lanthanide (Eu3+, Tb3+) / β-diketone modified mesoporous SBA-15 / organic polymer hybrids: chemically bonded construction, physical Characterization, and photophysical properties”, Inorg. Chem. 2009, 48, 8276-8285.

45. X. F. Qiao, B. Yan*, “Lanthanide centers / functionalized TTA/ silicon-oxygen network / polyethylene glycol hybrid materials: chemically bonded assembly, physical characterization and luminescence”, J. Phys. Chem. B 2009, 113, 11865-11875.

46. F. Lei, B. Yan*, H. H. Chen, J. T. Zhao, “Template-directed route to fabricate Eu3+-doped white light hydroxyl sodium yttrium tungstate monodisperse microarchitectures and their conversion to NaY(WO4)2”, Inorg. Chem. 2009, 48, 7576-7584.

47. F. Lei, B. Yan*, H. H. Chen, J. T. Zhao, “Surfactant-assisted hydrothermal synthesis, physical characterization and photoluminescence of PbWO4”, Cryst. Growth Des. 2009, 9, 3730-3736.

48. X. F. Qiao, B. Yan*, “Hybrid materials of lanthanide centers / functionalized β-diketone / silicon-oxygen network / polymeric chain: coordination bonded assembly, physical characterization and photoluminescence”,Inorg. Chem. 2009, 48, 4714-4723.

49. H. F. Lu, B. Yan*, J. L. Liu,“Functionalization of calix[4]arene as molecular bridge to assemble novel luminescent lanthanide supramolecular hybrid systems”, Inorg. Chem. 2009, 48, 3966-3975.

50. B. Yan*, Y. Li, B. Zhou, “Covalently bonding assembly and photophysical properties of luminescent molecular hybrids Eu-TTA-Si and Eu-TTASi-MCM-41 by modified thenoyltrifluoroacetone”, Microp. Mesop. Mater. 2009, 120, 317-324.

51. F. Lei, B. Yan*, H. H. Chen,“Morphology controlled synthesis, physical characterization and photoluminescence of novel self-assembled pompon-like white light phosphor: Eu3+-doped sodium gadolinium tungstate”, J. Phys. Chem. C 2009, 113, 1074-1082.

52. X. Z. Xiao, B. Yan*, Y. S. Song, “GdPxV1-xO4: Eu3+ nanophosphors and hydrated Zn3(PO4)2: Eu3+ nano-rod bunches: facile reproducible hydrothermal synthesis, controlled microstructure and photoluminescence”, Cryst. Growth Des. 2009, 9, 136-144.

53. B. Yan*,Q. M. Wang, D. J. Ma, “Photophysical properties of supramolecular lanthanide- calix[4]arene covalently bonded hybrid systems: constructed through base-initiated nucleophilic addition”, Inorg. Chem. 2009, 48, 36-44.

54. X. F. Qiao, B. Yan*, “Assembly, characterization and photoluminescence of hybrids containing europium (III) complexes covalently bonded to inorganic Si-O networks / organic polymers by modified β-diketone”, J. Phys. Chem. B 2008, 112, 14742-14750.

55. Z. Q. He, X. Xu, S. Song*, L. Xie, J. J. Tu, J. M. Chen, B. Yan*, “A visiblelight-driven titanium dioxide photocatalyst codoped with lanthanum and iodine: an application in the degradation of oxalic acid”, J. Phys. Chem. C 2008, 112, 16431-18437.

56. J. L. Liu, B. Yan*, “Lanthanide (Eu3+, Tb3+) centered hybrid materials using modified Functional bridge chemical bonded with silica: molecular design, physical characterization and photophysical properties”, J. Phys. Chem. B. 2008, 112, 10898-10907.

57. J. L. Liu, B. Yan*, “Molecular construction and photophysical properties of Luminescent covalently bonded lanthanide hybrid materials: organic ligands containing 1,2,4-triazole grafted with silica by mercapto modification”, J. Phys. Chem. C. 2008, 112, 14168 - 14178.

58. B. Yan*, H. F. Lu, “Lanthanide centered covalently bonded hybrids through sulfide linkage: molecular assembly, physical characterization and photoluminescence”, Inorg. Chem. 2008,47, 5601-5611.

59. B. Yan*, Q. M. Wang, “First two luminescent molecular hybrids composed of bridged Eu(III)-b-diketone chelates covalently trapped in silica and titanate gels”, Cryst. Growth Des. 2008, 8, 1484-1489.

60. S. Song, L. J. Xu, Z. Q. He*, H. P. Ying, J. M. Chen, X. Z. Xiao, B. Yan*, “Photocatalytic degradation of CI direct Red 23 in aqueous solutions under UV irradiation using SrTiO3 / CeO2 composite as the catalyst”, J. Hazard. Mater. 2008, 152,1301-1308.

61. Y. Li, B. Yan*, H. Yang, “Construction,characterization and photoluminescence of mesoporous hybrids containing europium (III) complexes covalently bonded to SBA-15 directly functionalized by modified beta-diketone”, J. Phys. Chem. C 2008,112, 3959-3968.

62. B. Yan*, X. F. Qiao,“Rare earth / inorganic / organic polymeric hybrid materials: molecular assembly, regular microstructure and photoluminescence”, J. Phys. Chem. B 2007, 111, 12362-12374.

63. S. Song, L. J. Xu, Z. Q. He*, J. M. Chen, X. Z. Xiao, B. Yan*, “Mechanism of the Photocatalytic Degradation of C.I. Reactive Black 5 at pH 12.0 Using SrTiO3/CeO2 as the Catalyst”, Environ. Sci. Technol. 2007, 41, 5846-5853.

64. Q. M. Wang, B. Yan*, “A novel way to luminescent terbium molecular-scale hybrid materials: modified heterocyclic ligands covalently bonded with silica”, Cryst. Growth Des. 2005, 5, 497-503.

65. Q. M. Wang, B. Yan*, “Novel luminescent terbium molecular-based hybrids with modified meta aminobenzoic acid covalently bonded with silica”, J. Mater. Chem. 2004, 14, 2450-2454.