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Xiaoming ZHAO
Published:2016-10-17 Hits:854

Professor Dr. Xiaoming ZHAO




Xiaoming Zhao

School of Chemical Science and Engineering, Tongji University



Room 105, Chemistry Building & Room 205, Old News Center

Siping Road 1239, Shanghai 200092, P. R. China













Selected Publications:


[22] "Regioselective fluorination of 1-(2,2-dibromovinyl)benzene derivatives with wet tetran-bytylammonium fluoride: one-pot synthesis of (Z)-1-(2-bromo-1-fluorovinyl)benzenes",

Mingzhu Zhao, Ling Ming, Jialiang Tang and Xiaoming Zhao*,

Organic Letters, 2016, 18, 416-419.


[21] "Enantioselective synthesis of fluorinated branched allylic compounds via Ir-catalyzed allylations of functionalized fluorinated methylene derivatives",

Hongbo Zhang, Jiteng Chen, Xiaoming Zhao*

Org. Biomol. Chem., 2016, 14, 7183-7186 (This paper was highlighted in Synfacts, 2016, 16, 947).


[20] "Synthesis of chiral fluorine-containing compounds via Pd-catalyzed asymmetrical allylations of dimethyl 2-fluoromalonate using sulfonamide-pyridine ligands",

Min Zhang, Mingzhu Zhao, Purui Zheng, Hongbo Zhang, Xiaoming Zhao*

J. Fluorine Chem., 2016, 189, 13-21.


[19] "Synthesis of carbonyl 2-amino-pyrimidines via tandem regioselective heterocyclization of 1,3-diynes with guanidine and selective oxidation", Liang Zhang, Mingzhu Zhang and Xiaoming Zhao*,

Chem. Commun., 2015, 51, 9370-9373.


[18] "Regioselective formation of 2,4,5-trisubstituted oxazoles through transition-Metal free heterocyclization of 1,3-diynes with N,O-bis(trimethylsiyl)acetamide", Liang Zhang and Xiaoming Zhao*,

Organic Letters, 2015, 17, 184-186.


[17] "Enantioselective transformation of Na2SO3 into allylic sulfonic acids under Pd catalysis ", Wei Liu, Xiaoming Zhao*, Hong-bo Zhang, Liang Zhang,

Chem. Commun., 2015, 51, 655-657.


[16] "Enantioselective transformation of allyl carbonates into branched allyl carbamates using amines and recycling CO2 under iridium catalysis", Shengcai Zheng, Min Zhang, and Xiaoming Zhao*,

Chem. -Eur. J., 2014, 20, 7216-7221.


[15] "Enantioselective domino reaction of CO2, amine and allyl chloride under iridium catalysis: formation of allyl carbamates", Min Zhang, Xiaoming Zhao*, Shengcai Zheng,

Chem. Commun., 2014, 50, 4455-4458.


[14] "Asymmetric Synthesis of Allylic Sulfonic Acids: Enantio- and Regioselective Iridium-Catalyzed Allylations of Na2SO3", Wei Liu, Xiaoming Zhao*, Hongbo Zhang, Mingzhu Zhao,

Chem. -Eur. J., 2014, 20, 16873-16876(highlighted by both a Frontispiece paper in Chem.-Eur.J. and by ChemViews).


[13] " Highly regioselective iridium-catalyzed and samarium-promoted coupling of allylic carbonates with ketones: New approach toward homoallylic alcohols",
Wei Liu, Liang Zhang, Weikang Yang, and Xiaoming Zhao*
RSC Advances, 2013, 3, 19917-19919.


[12] " Synthesis of 2,5-disubstituted thiophenes via metal-free sulfur heterocyclization of 1,3-diynes with sodium hydrosulfide",
Jialiang Tang, and Xiaoming Zhao*
RSC Advances, 2012, 2, 5488–5490.


[11] "One pot iridium-catalyzed asymmetrical double allylaitons of sodium Sulfide: a fast and economic way to construct chiral C2-symmetric bis(1-substituted-allyl)sulfane",
Shengcai Zheng, Weiqing Huang, Ning Gao, Ruimin Cui, Min Zhang, and Xiaoming Zhao*
Chem. Commun., 2011, 45, 6969-6971.


[10] "Carbon-sulfur bond formaton via Iridium-catalyzed asymmetrical allylation of aliphatic thiols"
Ning Gao, Shengcai Zheng, Weikang Yang, and Xiaoming Zhao*
Organic Letters, 2011, 13, 1514-1516 (This paper was highlighted by Organic Chemistry Portal, 2011, Dec, see: www.organic-chemistry.org/abstracts/lit3/207.shtm). 


[9] "Regio- and Enantioselective Iridium-Catalyzed Allylation of Thiophenol: Synthesis of Enantiopure Allyl Phenyl Sulfides"  
Shengcai Zheng,  Ning Gao, Wei Liu, Dongge Liu, Xiaoming Zhao,* and Theodore Cohen
Organic Letters, 2010, 12, 4454-4457 (This paper was highlighted in Synfacts, 2010, 12, 1400).


[8] "Readily Prepared 3-Chloro-1-(phenylthio)propene, a Versatile Three-Carbon Annulating Agent"
Taoping Liu, Xiaoming Zhao*, Long Lu, and Theodore Cohen*  
Organic Letters, 2009, 11, 4576-4579.


[7] "Iridium-catalyzed Regio- and Enantioselective Allylic Alkylation of Fluorobis(phenylsulfonyl)methane"
Wenbo Liu, Shengcai Zheng, Hu He, Xiaoming Zhao*, Lixin Dai, and Shuli You *
Chem. Commun., 2009, 43, 6604-6606.


[6] "Iridium-Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A Csp3-H Bond Activation a to the Trifluoromethyl Group"
Y. Guo; X. Zhao; D. Zhang; S-I. Murahashi 
Angew. Chem. Int. Ed., 2009, 48, 2047-2049.


[5] "Efficient 1,4-addition of a-substituted fluoro(phenylsulfonyl)methane derivatives to a,b-unsaturated compounds"
G. K. Surya Prakash,* Xiaoming Zhao, Sujith Chacko, Fang Wang, Habiba, Vaghoo, and George A. Olah*
Beil. J. Org. Chem., 2008, 4, No. 17.


[4] "2-Phenylthio-3-bromopropene, a Valuable Synthons, Easily Prepared by a Simple Rearrangement"
Wenbo Chen, Xiaoming Zhao,* Long Lu and T. Cohen*
Organic Letters, 2006, 8, 2807-2090. 


[3] " The triplet state in Pt-acetylide oligomers, polymers and copolymers",

E. E. Silverman, T. Cardolaccia, Xiaoming Zhao, K.Y. Kim, K. H. Glusac, Kirk S. Schanze*

Coordination Chemistry Reviews, 2005, 249, 1491–1500 (IF 12.2 ).


[2] " A Platinum Acetylide Polymer with Sterically Demanding Substituents: Effect of Aggregation on the Triplet Excited State"
Xiaoming Zhao, Thomas Cardolaccia, Richard Farley, Khalil A. Abboud and Kirk S. Schanze.
Inorganic Chemistry, 2005, 44, 2619-2627 (IF 3.3).


[1] " Bis-silyl substituted ferrocenylenes, including dicyanovinyl electron-withdrawing groups, as potential non-linear optical materials"
Xiaoming Zhao, Hemant Sharma, Francisco Cervantes-Lee and Keith H. Pannell, Gary J. Long, Ahmed M. Shahin
J. Organomet. Chem., 2003, 686, 235-241 (IF 2.04).

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