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赵晓明
发表时间:2015-03-10 阅读次数:6377次

赵晓明

 

赵晓明  博士  教授  博士生导师
联系电话:65981376
Email:xmzhao08@tongji.edu.cn
专业方向:有机化学
办公室:原新闻中心205室&化学馆105室
研究方向:有机氟化学、不对称催化及材料化学

个人介绍

The biographical sketch

Xiao-Ming Zhao obtained his Ph.D. from Daliang University of Technology in 1995.  Then, he did postdoctoral research at the University of Florida (UF) and University of Southern California (USC) in the group of Prof G.K.Prakash and Prof G.A.Olah.  He is currently a professor in Tongji University at Shanghai.  His research group’s interests were recognized by the award of a Thieme Chemistry Journal Award in 2012 and focus on reaction design, asymmetric synthesis and fluorine chemistry.

 


男,博士,2008年4月 经同济大学全球人才招聘进入同济工作,任教授、博士生导师。
毕业于大连理工大学。1998启留学美国八年。于佛罗里达大学、南加州大学等做博士后、高级副研究员。1995-1998及2004-2006于中国科学院上海有机化学有机所博士后学习与工作,任副研究员(短期在日本 S.I. Murahashi 教授组做访问教授)。归国后的研究受到国际同行关注,应邀在 Synthesis (2013, 45, 2051-69) 撰写综述,介绍成果。

 

个人荣誉与奖励:

2010 年入选上海市“浦江人才”。
2012 年获得由国际主流期刊
《合成》(Synlett, Synthesis and Synfacts) 评选的 “Thieme化学期刊奖 (Thieme Chemistry Journal Award 2012)” 。


研究方向:
设计和发现新反应,并将其发展为有用的合成方法,用于目标分子(如药物,功能材料等)或天然产物的合成。

有机氟化学包括:氟化试剂、氟化方法、含氟材料等研究。

有机材料化学如:液晶,非线性材料,荧光和磷光材料等。 

科研: 主持国家“自然基金项目”、上海市“浦江人才项目”和“教委重大创新项目”等多项,以及与企业合作项目。

教学: 主讲本科生和研究生的双语《有机化学》、《现代有机化学》、《绿色化学》、《精细有机合成新方法》等课程。
 

 

获奖成员:
博士生:郑生才(获2010“优秀研究生”奖、2011“陶氏化学”特等奖、2012“国家奖学金”)。 
高宁(同济保送攻博,获2011“倪天增”奖、2012“优秀研究生奖”、2013“国家奖学金”)。
刘炜(获2012“和氏璧”奖、2013“优秀研究生奖”、2014“和氏璧奖”)。
张敏 (硕转博,获2013“和氏璧”奖)。

赵明珠(获2016“光华奖”)。

郑璞睿 (2014同济保送攻博)。

陈骥腾(2015同济保送攻博)。
硕士生:唐佳亮(获2012“光华奖”)。刘海征 (获2013“陶氏优秀奖”)。张亮(获2014“和氏璧奖”)。

 

List of publications
发表的论文:

[22] "Ag-assisted fluorination of unprotected 4,6-disubstituted 2-aminopyrimidines with Selectfluor" ,

Chenxi Wang, Juewang Cai, Min Zhang, and Xiaoming Zhao*,

J. Org. Chem., 2017, 82, 1260-1265.

[21] "Regioselective fluorination of 1-(2,2-dibromovinyl)benzene derivatives with wet tetran-bytylammonium fluoride: one-pot synthesis of (Z)-1-(2-bromo-1-fluorovinyl)benzenes",

Mingzhu Zhao, Ling Ming, Jialiang Tang and Xiaoming Zhao*,

Organic Letters, 2016, 18, 416-419 (This paper was highlighted by Organic Chemistry Portal, 2017, Jan, see: www.organic-chemistry.org/abstracts/lit5/277.shtm).

[20] "Enantioselective synthesis of fluorinated branched allylic compounds via Ir-catalyzed allylations of functionalized fluorinated methylene derivatives",

Hongbo Zhang, Jiteng Chen, Xiaoming Zhao*

Org. Biomol. Chem., 2016, 14, 7183-7186 (This paper was highlighted in Synfacts, 2016, 16, 947).

[19] "Synthesis of carbonyl 2-amino-pyrimidines via tandem regioselective heterocyclization of 1,3-diynes with guanidine and selective oxidation", Liang Zhang, Mingzhu Zhang and Xiaoming Zhao*,

Chem. Commun., 2015, 51, 9370-9373.

[18] "Regioselective formation of 2,4,5-trisubstituted oxazoles through transition-Metal free heterocyclization of 1,3-diynes with N,O-bis(trimethylsiyl)acetamide", Liang Zhang and Xiaoming Zhao*,

Organic Letters, 2015, 17, 184-186.

[17] "Enantioselective transformation of Na2SO3 into allylic sulfonic acids under Pd catalysis ", Wei Liu, Xiaoming Zhao*, Hong-bo Zhang, Liang Zhang,

Chem. Commun., 2015, 51, 655-657.

[16] "Enantioselective transformation of allyl carbonates into branched allyl carbamates using amines and recycling CO2 under iridium catalysis", Shengcai Zheng, Min Zhang, and Xiaoming Zhao*,

Chem. A -Eur. J., 2014, 20, 7216-7221.

[15] "Enantioselective domino reaction of CO2, amine and allyl chloride under iridium catalysis: formation of allyl carbamates", Min Zhang, Xiaoming Zhao*, Shengcai Zheng,

Chem. Commun., 2014, 50, 4455-4458.

[14] "Asymmetric Synthesis of Allylic Sulfonic Acids: Enantio- and Regioselective Iridium-Catalyzed Allylations of Na2SO3", Wei Liu, Xiaoming Zhao*, Hongbo Zhang, Mingzhu Zhao,

Chem. A -Eur. J., 2014, 20, 16873-16876(highlighted by both a Frontispiece paper in Chem.A -Eur. J. and by ChemViews).

[13] " Highly regioselective iridium-catalyzed and samarium-promoted coupling of allylic carbonates with ketones: New approach toward homoallylic alcohols",
Wei Liu, Liang Zhang, Weikang Yang, and Xiaoming Zhao*
RSC Advances, 2013, 3, 19917-19919.
[12] "Synthesis of 2,5-disubstituted thiophenes via metal-free sulfur heterocyclization of 1,3-diynes with sodium hydrosulfide",
Jialiang Tang, and Xiaoming Zhao*
RSC Advances, 2012, 2, 5488–5490.
[11] "One pot iridium-catalyzed asymmetrical double allylaitons of sodium Sulfide: a fast and economic way to construct chiral C2-symmetric bis(1-substituted-allyl)sulfane",
Shengcai Zheng, Weiqing Huang, Ning Gao, Ruimin Cui, Min Zhang, and Xiaoming Zhao*
Chem. Commun., 2011, 45, 6969-6971.
[10] "Carbon-sulfur bond formaton via Iridium-catalyzed asymmetrical allylation of aliphatic thiols"
Ning Gao, Shengcai Zheng, Weikang Yang, and Xiaoming Zhao*
Organic Letters, 2011, 13, 1514-1516 (This paper was highlighted by Organic Chemistry Portal, 2011, Dec, see: www.organic-chemistry.org/abstracts/lit3/207.shtm). 

[9] "Regio- and Enantioselective Iridium-Catalyzed Allylation of Thiophenol: Synthesis of Enantiopure Allyl Phenyl Sulfides"  
Shengcai Zheng,  Ning Gao, Wei Liu, Dongge Liu, Xiaoming Zhao,* and Theodore Cohen
Organic Letters, 2010, 12, 4454-4457 (This paper was highlighted in Synfacts, 2010, 12, 1400).
[8] "Readily Prepared 3-Chloro-1-(phenylthio)propene, a Versatile Three-Carbon Annulating Agent"
Taoping Liu, Xiaoming Zhao*, Long Lu, and Theodore Cohen  
Organic Letters, 2009, 11, 4576-4579.

[7] "Iridium-catalyzed Regio- and Enantioselective Allylic Alkylation of Fluorobis(phenylsulfonyl)methane"
Wenbo Liu, Shengcai Zheng, Hu He, Xiaoming Zhao*, Lixin Dai, Shuli You*
Chem. Commun., 2009, 43, 6604-6606.

[6] "2-Phenylthio-3-bromopropene, a Valuable Synthons, Easily Prepared by a Simple Rearrangement"
Wenbo Chen, Xiaoming Zhao*, Long Lu and T. Cohen
Organic Letters, 2006, 8, 2807-2090.

 

归国前的代表工作:

[5] "Iridium-Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A Csp3-H Bond Activation a to the Trifluoromethyl Group"
Y. Guo; X. Zhao; D. Zhang; S-I. Murahashi 
Angew. Chem. Int. Ed., 2009, 48, 2047-2049.
[4] "Efficient 1,4-addition of a-substituted fluoro(phenylsulfonyl)methane derivatives to a,b-unsaturated compounds"
G. K. Surya Prakash,* Xiaoming Zhao, Sujith Chacko, Fang Wang, Habiba, Vaghoo, and George A. Olah*
Beil. J. Org. Chem., 2008, 4, No. 17.
[3] "The triplet state in Pt-acetylide oligomers, polymers and copolymers",

E. E. Silverman, T. Cardolaccia, Xiaoming Zhao, K.Y. Kim, K. H. Glusac, Kirk S. Schanze*

Coordination Chemistry Reviews, 2005, 249, 1491–1500.

[2] " A Platinum Acetylide Polymer with Sterically Demanding Substituents: Effect of Aggregation on the Triplet Excited State"
Xiaoming Zhao, Thomas Cardolaccia, Richard Farley, Khalil A. Abboud and Kirk S. Schanze.
Inorganic Chemistry, 2005, 44, 2619-2627.
[1] " Bis-silyl substituted ferrocenylenes, including dicyanovinyl electron-withdrawing groups, as potential non-linear optical materials"
Xiaoming Zhao, Hemant Sharma, Francisco Cervantes-Lee and Keith H. Pannell, Gary J. Long, Ahmed M. Shahin
J. Organomet. Chem., 2003, 686, 235-241.

 

已授权专利:

[1] 赵晓明,明玲,“E)-245-三取代-(1-丙烯基)噁唑环类化合物及合成方法和应用” ,专利号:201310719833.9,2014

[2] 赵晓明,高宁,“一种邻氨基苯手性烯丙基硫醚化合物及其制备方法” ,专利号:201110351007.4,2016

[3] 赵晓明,明玲,“一种(Z)-2-溴-1-氟芳香族烯烃类化合物及其合成方法和用途” ,专利号:201310719547.2,2014

[4] 赵晓明,郑生财,“一种3-芳(烷)基硫取代-1-丙烯类化合物及其合成方法” ,专利号:201010115243.1,2014

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